ChemicalBook > CAS DataBase List > Ethyl 4-[[(methylphenylamino)methylene]amino]benzoate

Ethyl 4-[[(methylphenylamino)methylene]amino]benzoate

Product Name
Ethyl 4-[[(methylphenylamino)methylene]amino]benzoate
CAS No.
57834-33-0
Chemical Name
Ethyl 4-[[(methylphenylamino)methylene]amino]benzoate
Synonyms
UV Absorbers;UV Stabilizer UV-1;milestab 1;YISTAB UV-1;LOTSORB UV 1;Runsorb UV-1;Sinosorb? UV-1;Absorbent UV-1;UV absorber UV-1;UvAbsorberUv-1>98.5%
CBNumber
CB4295255
Molecular Formula
C17H18N2O2
Formula Weight
282.34
MOL File
57834-33-0.mol
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Ethyl 4-[[(methylphenylamino)methylene]amino]benzoate Property

Boiling point:
188 °C(Press: 0.1 Torr)
Density 
1.05±0.1 g/cm3(Predicted)
vapor pressure 
78Pa at 25℃
storage temp. 
Sealed in dry,Room Temperature
solubility 
Chloroform (Slightly), Ethyl Acetate (Slightly)
form 
Light Yellow to Yellow Semi-Solid
pka
6.94±0.50(Predicted)
Water Solubility 
34.7mg/L at 20℃
LogP
4.46 at 25℃
CAS DataBase Reference
57834-33-0(CAS DataBase Reference)
EPA Substance Registry System
Benzoic acid, 4-[[(methylphenylamino)methylene]amino]-, ethyl ester (57834-33-0)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H373May cause damage to organs through prolonged or repeated exposure

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P314Get medical advice/attention if you feel unwell.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TRC
Product number
E925558
Product name
Ethyl4-[[(methylphenylamino)methylene]amino]benzoate
Packaging
250mg
Price
$155
Updated
2021/12/16
AK Scientific
Product number
P954
Product name
N-(Ethoxycarbonylphenyl)-N'-methyl-N'-phenylformamidine
Packaging
500g
Price
$150
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0079109
Product name
ETHYL 4-[[(METHYLPHENYLAMINO)METHYLENE]AMINO]BENZOATE
Purity
95.00%
Packaging
1G
Price
$903.5
Updated
2021/12/16
Alichem
Product number
57834330
Product name
Ethyl4-(((methyl(phenyl)amino)methylene)amino)benzoate
Packaging
500g
Price
$159
Updated
2021/12/16
Alichem
Product number
57834330
Product name
Ethyl4-(((methyl(phenyl)amino)methylene)amino)benzoate
Packaging
1000g
Price
$242.4
Updated
2021/12/16
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Ethyl 4-[[(methylphenylamino)methylene]amino]benzoate Chemical Properties,Usage,Production

Description

UV-1 is highly effective for the light stabilization of PUR in a wide range of applications, including microellular foams and integral skin foams for footwear, conventional rigid and flexible foams, fabric coatings for artificial leather, adhesives, sealants, and elastomers (spray, RIM, etc.). lItis conveniently added to PUR systems as a solution in the polyol component (polyether- or polyester-based).

Physical properties

UV-1(Ethyl 4-[[(methylphenylamino)methylene]amino]benzoate) is a high efficient anti-ultraviolet additive. It is widely used in adhesives, polyurethane, foam and other materials. Because of its excellent absorption property, the ultraviolet radiation in 240-340nm is effectively absorbed and the ultraviolet radiation in the 300-330nm is nearly absorbed completely. Its anti-ultraviolet effect is 1.1-1.4 times as efficient as the UV absorbers of benzophenone or benzotriazole types.

Uses

UV-1(Ethyl 4-[[(methylphenylamino)methylene]amino]benzoate) has good effect on the polymer system and it has good compatibility with the resin. The anti-yellowing effect is excellent. Its effect is superior to the other UV agent for PU. It is widely used in PU foaming, PU coating, PU leather, PU board and resins etc.

Industrial uses

UV absorber UV-1 is a liquid formamidine type ultraviolet absorber, it has a very strong UV absorption spectrum peak between 300-330nm, in this region polyurethane is susceptible to radiation degradation. So it has excellent light stability to microporous polyurethane products such as foam, integral skin foam, traditional foam, semi-rigid, soft foam, fabric coating, some adhesives, sealants and elastomers.It is convenient to use and miscible with polyester polyol and polyether polyols, has high solubility in many solvents, and has good compatibility with isocyanates and other polyurethane additives(such as light stabilizer 292).In polyurethane,normal usage level range is 0.2-1.0%.In adhesives and sealant,concentration level normally range is 0.5-1.0%.

Synthesis


165 g (1 mol) of ethyl p-aminobenzoate, 117.7 g (1.1 mol) of N-methylaniline, 10 g of p-toluenesulfonic acid,200mL with toluene toluene added to the 1000mL reaction flask, stirred and warmed to 50-60 ?? C, 2h dropwise 59.53g (1.1mol) formic acid(Content of 85%),Heating to reflux reaction, continue to separate the generated water, the reaction of about 5h to stop water when there is no water. The reaction solution was distilled off with atmospheric toluene recovery agent, toluene was recovered, the remaining vacuum distillation reaction solution,A pale yellow viscous liquid N- (4-ethoxycarbonylphenyl) -N'-methyl-N'-phenyl formamidine 262g, yield 93%, purity 99.4%.

Ethyl 4-[[(methylphenylamino)methylene]amino]benzoate Preparation Products And Raw materials

Raw materials

Preparation Products

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Ethyl 4-[[(methylphenylamino)methylene]amino]benzoate Suppliers

Aladdin Scientific
Tel
+1-833-552-7181
Email
sales@aladdinsci.com
Country
United States
ProdList
57511
Advantage
58
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View Lastest Price from Ethyl 4-[[(methylphenylamino)methylene]amino]benzoate manufacturers

Qingdao Truelight functional Material Technology Co., Ltd.
Product
UV ABSORBER TRUELICHT UV1 57834-33-0
Price
US $0.00/KG
Min. Order
1KG
Purity
98.0%
Supply Ability
20 tons
Release date
2023-05-03
Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
Ultraviolet Absorbent UV-1
Price
US $120.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20ton
Release date
2024-04-25
Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
Absorbent UV-1 57834-33-0
Price
US $200.00-95.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20ton
Release date
2024-04-25

57834-33-0, Ethyl 4-[[(methylphenylamino)methylene]amino]benzoateRelated Search:


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  • (E)-Ethyl 4-[[(Methylphenylamino)Methylene]Amino]Benzoate
  • Ethyl 4-[[(methylphenylamino)methylene]amino]benzoate(UV-1)
  • Light Stablizer UV-1
  • UV Absorbers
  • Ultraviolet absorber UV-1
  • ETHYL 4-[[(METHYLPHENYLAMINO)METHYLENE]AMINO]BENZOATE 57834-33-0
  • UV ABSORBER TRUELICHT UV1
  • UV absorber Sunsorb 1
  • YISTAB UV-1
  • Sinosorb? UV-1
  • Absorbent UV-1
  • 57834-33-0
  • 57843-33-0
  • 1104810-48-2
  • C17H18N2O2
  • C15H14N2O2
  • 57834-33-0